I study how crystals form, especially nucleation. Nucleation is the first step in the formation of a crystal, and it is a rare (and so elusive) event in the sense that only one nucleation event is required to make a crystal.
Computer simulation studies of crystallisation
Crystallisation can be complex, here is nanocrystalline state, that forms as an intermediate in computer simulation studies of crystallisation of a simple model (Stillinger’s Gaussian Core Model). There is only type of (spherical) particle present, but the particles are coloured according to their local environment. Yellow, orange and green particles are all locally crystalline, but are in three different crystal lattices. Purple particles are at (mainly crystal/crystal interfaces). Yellow atoms are in locally face-centred (fcc) cubic environments, while orange atoms are hexagonal close packed (hcp) and green atoms are body-centred cubic (bcc). The blue atoms are disordered. As you can see the state is nanocrystalline in the sense that it is a mixture of nanoscale, i.e., very small, crystals of the three different crystal lattices.
Experiments on crystallisation from solution
A co-supervised experimental PhD student has just graduated. Last year, we published a paper (pdf & supp info) on the crystallisation of the small molecule glycine from solution. Another paper, on the nucleation of the competing forms (polymorphs) of glycine crystals, is in the works.
In 2014, I wrote a review of quantitative experimental data on nucleation at constant supersaturation, plus the models used to understand this data. It was published in CrystEngComm (open access). The review covers a few aspects of the nucleation of crystals, but looks in a fair amount of detail at observations that in some crystallising systems, the rate at which crystals form (nucleate) can vary by orders of magnitude between one droplet and another apparently identical droplet.